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水溶性噻二唑衍生物的合成及其摩擦学性能研究
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    摘要:

    合成一种新型水溶性噻二唑衍生物,采用红外光谱仪对其结构进行表征,采用SRV摩擦磨损试验机考察其在三乙醇胺水溶液中的摩擦学性能,采用表面轮廓仪及扫描电子显微镜观察磨斑表面形貌。SRV摩擦实验结果表明,该添加剂能显著改善三乙醇胺基础液的抗磨减摩性能,并能有效避免疲劳磨损;XPS结果显示,添加剂通过与摩擦副表面的摩擦反应生成FeS及Fe2O3等反应膜,起到极压抗磨的效果;同时该添加剂还具有很好的抑制铜片腐蚀的性能,是一种环境友好的多功能润滑添加剂。

    Abstract:

    A new type of water soluble thiadiazole derivative was synthesized and its structure was analyzed through infrared spectrum.The tribological properties of thiadiazole derivative as additive in triethanolamine auqeous solution were evaluated with SRV oscillating friction and wear tester.The worn surfaces were observed with surfaces profiler apparatus and scanning electron microscopy.The results of SRV test indicate that the thiadiazole derivative as additive in triethanolamine auqeous solution shows well anti wear and friction reducing properties,which can effectively reduce the fatigue wear.XPS analysis shows that a protective film composed of FeS and FeS2 compounds is formed on the worn surface due to the friction chemical reaction between the additive and the friction pair surface.The additive has excellent inhibition property as copper corrosion inhibitor,it is a promising as a multi functional environmental friendly lubricating additive.

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王建华,张文田,尚培华.水溶性噻二唑衍生物的合成及其摩擦学性能研究[J].润滑与密封,2014,39(7):102-106.
.[J]. Lubrication Engineering,2014,39(7):102-106.

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  • 在线发布日期: 2014-11-25
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