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离子液体对石墨烯润滑油分散及润滑性能的影响
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辽宁省自然科学基金项目(2019-ZD-0687);辽宁省教育厅项目(LJZ2017005);国家自然科学基金项目(51805336);中国热带农业科学院基本科研业务费专项基金项目(1630122019008);农业农村部热带作物产品加工重点实验室开放课题(KFKT201902)


Effect of Ionic Liquids on Dispersion and Lubricity of Graphene Lubricating Oil
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    摘要:

    研究离子液体作为添加剂对石墨烯润滑油分散和润滑性能的影响。通过改变离子液体质量分数、超声功率以及时间等条件,考察离子液体/石墨烯润滑油的分散稳定性;采用Rtec多功能摩擦磨损试验机,以Si3N4/钢为摩擦副,考察不同条件下离子液体/石墨烯润滑油的摩擦学行为;采用扫描电镜和超景深显微镜对磨损表面进行分析,探究离子液体作为添加剂的润滑机制。结果表明:离子液体质量分数为0.002 5%、超声时间为60 min,超声功率为600 W时石墨烯润滑油的分散性和稳定性均显著提高;加入离子液体后,石墨烯润滑油的润滑性能提高,其摩擦因数随离子液体质量分数的增加而下降,随超声功率的增加而降低,随超声时间的增加而增加。研究发现,由于离子液体阳离子的长链结构和自身黏度较大,离子液体构成的润滑膜较厚且易于吸附在摩擦副表面,并与石墨烯发生协同作用形成了混合润滑膜,从而避免了摩擦副之间的直接接触,改善了摩擦磨损性能。

    Abstract:

    The effects of ionic liquids as additives on the dispensability and lubricating properties of graphene lubricating oils were investigated.The dispersion stability of ionic liquid/graphene lubricating oil was investigated by changing the ionic liquid mass fraction,ultrasonic power and time.The tribological behaviors of ionic liquid/graphene lubricating oil under different conditions were investigated by using Rtec multi-functional friction and wear test machine and with Si3N4/steel as friction pair,and the worn surface was analyzed by scanning electron microscopy and ultra depth of field microscopy to explore the lubrication mechanism of ionic liquids as additives.The results show that the dispersibility and improved when the mass fraction of ionic liquid is 0.002 5%,the ultrasonic time is 60 min and ultrasonic power is 600 W.After the addition of ionic liquid/graphene,the lubrication performance of the lubricating oil is improved.The friction coefficient of lubricating oil is decreased with the increase of the mass fraction of the ionic liquid and the increase of the ultrasonic power,and increased with the increase of the ultrasonic time.It is found that due to the longchain structure of the ionic liquid cation and its high viscosity,the lubricating film composed of ionic liquid is thick and easy to be adsorbed on the surface of friction pair.And due to the synergistic effect of ionic liquid and graphene,the mixed lubricating film is formed,which avoids the direct contact between the friction pairs and improves the tribological performance.

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张丽秀,赵 越,魏晓奕,王俊海,喜冬阳,张 利.离子液体对石墨烯润滑油分散及润滑性能的影响[J].润滑与密封,2020,45(10):28-35.
ZHANG Lixiu, ZHAO Yue, WEI Xiaoyi, WANG Junhai, XI Dongyang, ZHANG Li. Effect of Ionic Liquids on Dispersion and Lubricity of Graphene Lubricating Oil[J]. Lubrication Engineering,2020,45(10):28-35.

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  • 在线发布日期: 2020-10-15
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