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球磨参数对石墨烯增强铜基复合材料性能的影响
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广西自然科学基金项目(2018GXNSFAA138183;2019GXNSFAA185052);国家级“大学生创新创业训练计划”项目(201710608026)


Effects of Ball-milling Parameters on Properties of Graphene Reinforced Copper-based Composites
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    摘要:

    采用粉末冶金法制备石墨烯增强铜基复合材料,研究全方位行星球磨机的球磨速度、球磨时间和球料比对复合材料的密度、显微硬度、导电率和拉伸性能的影响,并利用扫描电子显微镜(SEM)分析复合材料的显微形貌。结果表明:采用合适的球磨参数,石墨烯在铜基体中分散均匀;但球磨时间过长、球磨速度过快会导致石墨烯团聚,与铜基体之间的界面结合效果变差;随球料比的增加,复合材料的抗拉强度、延伸率和导电率明显改善;球磨速度为400 r/min时,显微硬度和导电率显示出相似的变化趋势。球磨时间直接影响石墨烯在铜基体中分散效果,球磨转速和球料比则影响铜粉颗粒的塑性变形以及石墨烯与铜基体的有效结合,当球料比为3∶1,球磨速度为300 r/min,球磨时间为6~8 h时复合材料的性能最优

    Abstract:

    Graphene reinforced copper-based composites were fabricated by powder metallurgy method.Effect of ballmilling speed,ballmilling time and ball-percentage of omnidirectional planetary ball mill on density,micro-hardness,conductivity and tensile properties were studied.The microscopic morphology of composites was analyzed by scanning electron microscope.The results show that graphene shows good dispersibility in copper matrix by using appropriate ball-milling parameters.Longer ball-milling time and quicker ball-milling speed generate aggregation of graphene,which results in weak bond between graphene and copper matrix.With the increase of ball material ratio,the conductivity,tensile strength and elongation of composites are improved.While the ball-milling speed is 400 r/min,the micro-hardness and conductivity of composites show similar trend.Ball milling time directly affects the dispersion effect of graphene in copper matrix,while ball milling speed and ball material ratio affect the plastic deformation of copper powder particles and the effective combination of graphene and copper matrix.In this experiment,the optimum ball-milling parameters are ball material ratio of 3∶1,ballmilling speed of 300 r/min and ball-milling time from 6 h to 8 h.

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文国富,梁艳娟,王秀飞,伊春强,尹彩流,蒙洁丽.球磨参数对石墨烯增强铜基复合材料性能的影响[J].润滑与密封,2021,46(1):103-110.
WEN Guofu, LIANG Yanjuan, WANG Xiufei, YI Chunqiang, YIN Cailiu, MENG Jieli. Effects of Ball-milling Parameters on Properties of Graphene Reinforced Copper-based Composites[J]. Lubrication Engineering,2021,46(1):103-110.

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  • 在线发布日期: 2021-02-22
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