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煤基浸锑石墨密封材料性能研究
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徐州市重点研发计划项目(KC19222);中央高校基本科研业务费专项资金项目(2019GF02)


Study on the Properties of Coalbased Antimony Graphite Sealing Materials
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    摘要:

    为提升石墨材料在高强度机械密封工况下的机械性能和密封性能,以煤炭加工的附加值产品(煤焦和沥青)为原料制备多孔石墨材料,然后通过高压浸锑制备煤基浸锑石墨密封材料;比较浸渍前后石墨材料的机械性能、微观结构差异、元素组成变化、摩擦磨损性能,分析浸渍锑后石墨材料性能的增强机制。结果表明:高压浸锑后石墨材料的机械强度和耐磨性能得到明显提升,其中密度增加了26.6%,抗压强度增加了114.3%,硬度增加了63.3%,气孔率下降了94%,绝对磨损量减少89.3%,平均摩擦因数降低了46.4%。高压浸锑后石墨材料中的孔隙被金属锑填充,并连接在一起形成条状,在摩擦磨损过程中充当骨架作用,从而提高石墨材料的抗磨性能;在浸锑石墨密封材料,微细网状的金属充填物可以减少材料的磨粒磨损,从而维持润滑膜的稳定,因而其可以作为高温等恶劣工况下的密封材料使用。

    Abstract:

    In order to improve the mechanical property and sealing property of graphite under the condition of high strength mechanical seal,porous graphite material was prepared from coal processing valueadded products (coal coke and asphalt),and then coalbased antimony graphite sealing material was prepared by highpressure antimony leaching.The mechanical properties,microstructure difference,element composition changes and friction and wear properties of graphite material before and after impregnation were compared,and the enhancement mechanism of graphite properties after impregnation was analyzed.The results show the mechanical strength and wear resistance of graphite material after highpressure antimony leaching are significantly improved,among which density is increased by 26.6%,compressive strength is increased by 114.3%,hardness is increased by 63.3%,porosity is decreased by 94%,absolute wear is decreased by 89.3%,and average friction coefficient is decreased by 46.4%.After antimony immersion at high pressure,the pores in the graphite material are filled with metallic antimony and are linked to form strips,which act as the skeleton during the friction and wear process,so the antiwear performance of the graphite material is improved.In the coalbased antimony graphite sealing materials,the fine mesh metal filling can reduce the abrasive wear of material,thus maintaining the stability of the lubrication film,so it can be used as a seal material under harsh conditions such as high temperature.

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于鸣泉,王启立,高晓峰,张锋涛,胡建文.煤基浸锑石墨密封材料性能研究[J].润滑与密封,2020,45(12):97-102.
YU Mingquan, WANG Qili, GAO Xiaofeng, ZHANG Fengtao, HU Jianwen. Study on the Properties of Coalbased Antimony Graphite Sealing Materials[J]. Lubrication Engineering,2020,45(12):97-102.

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  • 在线发布日期: 2021-04-22
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