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臭氧刻蚀改性Nomex/PTFE织物复合材料界面性能及摩擦学性能*
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国家自然科学基金项目(52005487;52075523)


Interface and Tribological Properties of O3-eteched Nomex/PTFE Fabric Composites
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    摘要:

    为提高Nomex/PTFE混编织物增强复合材料的界面性能和摩擦学性能,选用臭氧刻蚀改性方法对Nomex纤维和PTFE纤维进行表面改性,采用扫描电子显微镜(SEM)、接触角测定仪和能谱仪(EDS)研究臭氧刻蚀时间下纤维的表面形貌和官能团变化,采用多试件摩擦磨损试验机测试Nomex/PTFE织物复合材料的摩擦学性能,采用SEM和能谱仪(EDS)表征复合材料和对偶的磨损面。结果表明:臭氧刻蚀能够明显改变Nomex纤维和PTFE纤维的表面形貌,提高纤维的亲水性和与树脂的黏接性能,但会降低其力学性能;臭氧刻蚀处理后复合材料的界面性能和耐磨损性能有所提高,最优处理时间为1 h,磨损率可降低16.7%~20%。原因在于纤维表面粗糙度和含氧官能团的增加有利于提高纤维与树脂的界面结合强度,并减少作用力在材料界面上的应力集中效应。

    Abstract:

    In order to improve the interface and tribological properties of Nomex/PTFE hybrid fabric reinforced composite,the ozone oxidation was chosen to modify the surface of Nomex fiber and PTFE fiber.Effect of ozone treatment time on the morphologic and functional groups of Nomex and PTFE fiber were measured by scanning electron microscopy (SEM),energy-dispersive X-ray spectroscopy (EDS) and contact angle tester.The tribological properties of Nomex/PTFE hybrid fabric reinforced composite were evaluated by multi-specimen test machine and the worn surface of specimen and contact-pin were characterized by SEM and EDS.The test results indicate that the surface morphology of Nomex and PTFE fiber composite,the hydrophilicity of the fiber and the adhesion with the resin are significantly improved by ozone oxidation.However,the mechanical property of Nomex and PTFE fiber is reduced.The interface and tribological properties of the composite are improved after ozone oxidation and the optimal treatment time is 1 h.The wear rate is reduced by 16.7% to 20%.The ozone oxidation increases the surface roughness and the oxygen-containing functional group content of Nomex and PTFE fiber,which is beneficial to enhance the interfacial adhesion between fiber and resin,and reduce the stress concentration effect of the applied load on the fiber resin interface.

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李佩隆,张招柱*,杨明明,袁军亚,姜葳.臭氧刻蚀改性Nomex/PTFE织物复合材料界面性能及摩擦学性能*[J].润滑与密封,2022,47(10):1-8.
LI Peilong, ZHANG Zhaozhu*, YANG Mingming*, YUAN Junya, JIANG Wei. Interface and Tribological Properties of O3-eteched Nomex/PTFE Fabric Composites[J]. Lubrication Engineering,2022,47(10):1-8.

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  • 在线发布日期: 2023-01-11
  • 出版日期: 2022-10-15