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多晶及单晶铜的磨损及腐蚀性能研究
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Wear and Corrosion Properties of Polycrystalline and Monocrystalline Copper
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    摘要:

    对比研究多晶及单晶铜耐磨与耐腐蚀性能。在干摩擦条件不同载荷和速度下考察多晶及单晶铜的摩擦学性能;探讨多晶及单晶铜在35%NaCl溶液中的自然腐蚀及电化学腐蚀性能的差异。结果表明:在干摩擦及转速为100~400 r/min条件下,多晶铜的摩擦因数高于单晶铜,磨损量低于单晶铜;在干摩擦及载荷为20~35 N条件下,多晶铜摩擦因数高于单晶铜,磨损量无明显差异;单晶铜在NaCl溶液中比多晶铜具有较强的耐蚀性;多晶铜与45#钢磨损机制以黏着磨损为主,而单晶铜与45#钢的磨损机制以剥层磨损为主。接触表面塑性变形能力以及晶粒取向、晶界分布的差异是影响单晶铜和多晶铜磨损和腐蚀性能的主要原因;含有平直柱状晶晶界的单晶材料具有高取向性,有利于其大塑性变形;择优取向使单晶铜在晶胞尺度上的微观平面排列致密,同时晶界的减少抑制了腐蚀的扩展,从而提高了其耐蚀性。

    Abstract:

    Wear and corrosion resistance of polycrystalline copper (PC) and monocrystalline copper (MC) were studied comparatively.The friction and wear behaviors of MC and PC at different loads and sliding speeds under dry sliding conditions were studied.The difference of solution corrosion and electrochemical corrosion of MC and PC at 35% NaCl solution was investigated respectively.The results show that the friction coefficient of polycrystalline copper is higher than that of monocrystalline copper under the rotation speeds from 100 to 400 r/min and dry sliding conditions,while the wear loss of the polycrystalline copper is lower than that of monocrystalline copper.The friction coefficient of polycrystalline copper is higher than that of monocrystalline copper under the loads from 25 to 40 N and dry sliding conditions.MC has higher corrosion resistance than PM in the NaCl solution.The main mechanism of PC/steel is adhesive wear,and the main mechanism of MC/steel is delaminated wear.Different plastic deformation ability of contact surface,grain orientation and distribution of grain boundary can be attributed to different wear and corrosion behavior of MC and PC coupled with steels.MC has a high grain preferred orientation with columnar grain boundaries and can induce large plastic strain.The preferred orientation of grain makes MC has a dense arrange on the crystal plane in microstructure,and the decrease of grain boundaries inhibits the expansion of corrosion,so the corrosion resistance of MC is improved.

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商剑.多晶及单晶铜的磨损及腐蚀性能研究[J].润滑与密封,2018,43(8):104-108.
. Wear and Corrosion Properties of Polycrystalline and Monocrystalline Copper[J]. Lubrication Engineering,2018,43(8):104-108.

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  • 在线发布日期: 2018-09-03
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