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铜掺杂碳量子点宽温域减摩性能研究
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国家自然科学基金项目(51805336)


Research on Antifriction Performance of Copper Doped Carbon Quantum Dots in a Wide Temperature Range
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    摘要:

    为了改善宽温域下机械系统的摩擦性能,以葡萄糖酸铜和二乙烯三胺为原料,采用一步水热法合成铜掺杂碳量子点(Cu-CQDs)。将Cu-CQDs分散到PAO基础油中,在大气环境和不同温度下(25、100、200、300 ℃)考察含Cu-CQDs油样的摩擦学性能,并与含二烷基二硫代磷酸锌(ZDDP)油样进行比较。结果表明:Cu-CQDs和ZDDP都能增强PAO基础油的减摩抗磨性能,但Cu-CQDs性能优于ZDDP;特别在300 ℃时含Cu-CQDs油样减摩抗磨优势最为明显,300 ℃时其平均摩擦因数相较于PAO基础油降低了51%,相较于含ZDDP油样降低了11%。分析Cu-CQDs在高温下的摩擦机制,发现在高温摩擦时Cu-CQDs在摩擦副表面发生了复杂的摩擦化学反应,生成了一系列金属氧化物、碳化物和其他摩擦化学产物,这些物质在摩擦副表面形成了保护层,可有效缓解摩擦副接触摩擦。

    Abstract:

    To improve the friction performance of mechanical system in a wide temperature range,taking copper gluconate and diethylenetriamine as raw material,copper doped carbon quantum dots (Cu-CQDs) was synthesized with one-step hydrothermal method.Cu-CQDs was dispersed into PAO base oil,and the tribological properties of the oil sample containing Cu-CQDs were studied in atmospheric environment and at different temperatures(25 ℃,100 ℃,200 ℃,300 ℃).The results were compared with those of the oil sample containing zinc dialkyl dithiophosphate (ZDDP).The results indicate that Cu-CQDs and ZDDP can increase antifriction and wear resistant properties of PAO base oil,but the performance of Cu-CQDs is superior to that of ZDDP.Especially at 300 ℃,the oil sample containing Cu-CQDs has the most obvious antifriction and wear resistant advantages,its average friction coefficient decreases by 51% compared to PAO base oil and by 11% compared to oil sample containing ZDDP.The high temperature friction mechanism of Cu-CQDs was analyzed.It is found that Cu-CQDs undergoes complex frictional chemical reaction on the surface of the friction pair during high-temperature friction,generating a series of metal oxides,carbides,and other frictional chemical products.These substances form a protective layer on the surface of the friction pair,which has the effect of relieving the contact and friction of friction pair.

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陈士豪,王俊海,李新然,张丽秀,李婷.铜掺杂碳量子点宽温域减摩性能研究[J].润滑与密封,2024,49(3):90-96.
CHEN Shihao, WANG Junhai, LI Xinran, ZHANG Lixiu, LI Ting. Research on Antifriction Performance of Copper Doped Carbon Quantum Dots in a Wide Temperature Range[J]. Lubrication Engineering,2024,49(3):90-96.

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  • 在线发布日期: 2024-03-21
  • 出版日期: 2024-03-15