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液相浸渍法制备耐高温柔性石墨密封材料
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中央高校基本科研业务费资助项目(2020IVA022).


Preparation of High Temperature Resistant Flexible Graphite Sealing Material by Liquid Phase Impregnation Method
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    摘要:

    为提高柔性石墨密封材料的高温抗氧化性及力学性能,选用硼酸镁、磷酸、硅酸钠及乙二醇为浸渍剂,采用液相浸渍法对柔性石墨材料进行改性,并通过单因素条件实验确定最佳浸渍剂配比和浸渍工艺。结果表明:采用最佳工艺制备的柔性石墨材料抗拉强度、压缩率和泄漏率有明显的提高,且耐受温度从450 ℃提高至800 ℃,在800 ℃有氧环境焙烧1 h的热失重百分比下降到6.98%,表明液相浸渍有效提高了柔性石墨材料的耐高温性能,同时使材料的力学性能得到增强。SEM分析结果表明,硼酸镁、磷酸、硅酸钠在高温下在柔性石墨的内部和表面形成一层玻璃态保护层,并填充堵塞内部的微细孔道,隔绝氧气与石墨的接触,延缓柔性石墨与氧气的氧化反应。

    Abstract:

    In order to improve the oxidation resistance and mechanical properties of flexible graphite materials,by using magnesium borate,phosphoric acid,sodium silicate and ethylene glycol as impregnants,the flexible graphite materials were modified by liquid-phase impregnation method,and the optimum impregnant ratio and impregnation process were determined by single factor experiment.The results show that the tensile strength,compression rate and leakage rate of the high temperature resistant flexible graphite materials prepared by the optimum conditions are significantly improved,the tolerance temperature of the prepared flexible graphite material is increased from 450 ℃ to 800 ℃.The percentage of thermal weight loss after calcination at 800 ℃ in an aerobic environment for 1 h is decreased to 6.98%,indicating that liquid impregnation can effectively improve the hightemperature resistance of flexible graphite materials and enhance the mechanical properties of the materials.SEM analysis results show that magnesium borate,phosphoric acid and sodium silicate form a glasslike protective layer inside and on the surface of flexible graphite at high temperature,and fill the micro pores inside to block the contact between oxygen and graphite,which isolate the contact between oxygen and graphite,and delay the oxidation reaction between flexible graphite and oxygen.

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徐文露,张凌燕,邱杨率,王靖,赵绍林.液相浸渍法制备耐高温柔性石墨密封材料[J].润滑与密封,2021,46(6):78-83.
XU Wenlu, ZHANG Lingyan, QIU Yangshuai, WANG Jing, ZHAO Shaolin. Preparation of High Temperature Resistant Flexible Graphite Sealing Material by Liquid Phase Impregnation Method[J]. Lubrication Engineering,2021,46(6):78-83.

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  • 在线发布日期: 2022-04-07
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