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SiO2表面金属包覆处理对铜基粉末冶金材料制动摩擦磨损性能的影响
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国家自然科学基金项目 (U1804252);清华大学高端装备界面科学与技术全国重点实验室开放基金项目 (SKLTKF21B10); 河南省科技攻关项目 (212102210433);河南省自然科学基金项目(202300410143)


Effect of SiO2 Surface Metal Coating Treatment on the Braking Friction and Wear Properties of Cu-Based Powder Metallurgy Materials
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    摘要:

    为改善摩擦组元SiO2颗粒与铜基体间界面结合性能,通过表面金属包覆处理的方式制备铜包覆SiO2。分别以铜包覆SiO2和普通SiO2颗粒作为摩擦组元之一,利用SPS烧结技术制备2种铜基粉末冶金摩擦材料。分析2种摩擦材料的微观组织、力学及物理性能,在MM1000-Ⅱ型惯性制动试验台上测试2种摩擦材料的制动摩擦磨损性能,并对2种摩擦材料的摩擦表面及其三维形貌特征、磨屑特征和摩擦表面物相进行微观分析,研究SiO2表面金属包覆处理对制动条件下铜基粉末冶金材料摩擦磨损性能的影响。结果表明:经铜包覆处理的SiO2与Cu基体间的界面结合性能明显改善,提高了材料的硬度、致密度及导热系数,特别是导热系数得到了显著提升;随着制动初速度的升高,2种摩擦材料的平均摩擦因数均呈现先上升后下降的趋势;在相同的制动条件下,与含普通SiO2材料相比,除了制动压力为0.8 MPa、制动初速度为100 km/h外,在其他各制动条件下含铜包覆SiO2材料具有较高的平均摩擦因数和较低的磨损率,且其摩擦表面更为平整;提高制动初速度均能够促进2种摩擦材料表面形成以氧化膜为主的摩擦膜,且含铜包覆SiO2材料的摩擦膜更均匀,因而保护作用更好,即磨损率低。

    Abstract:

    To improve the interfacial bonding performance between friction component SiO2 particles and copper matrix.Two copper-based powder metallurgy friction materials were prepared by using SPS sintering technology with Cu-coated SiO2 and uncoated SiO2 particles as one of the friction components.The microstructure,mechanical and physical properties of the two friction materials were analyzed,and the braking friction and wear properties were tested on the MM1000-Ⅱ inertia braking test bench.The microscopic analyses on the features of friction surfaces and 3D morphology,wear debris and surface phases of the two friction materials were carried out,and the influences of metal coating on SiO2 surface on braking friction and wear properties of copper-based powder metallurgical friction material were studied.The results show that the Cu-coating treatment of SiO2 can strengthen the interface bond between SiO2 and copper matrix and improve the hardness,density and thermal conductivity of material,especially a significant increase in thermal conductivity.With the increase of the initial braking speed,the average friction coefficients of the two friction materials show a trend of increasing first and then decreasing.Under the same braking conditions,compared with ordinary SiO2 materials,except that the braking condition of pressure of 0.8 MPa and initial braking speed of 100 km/h,the copper-coated SiO2 containing material has higher average friction coefficient and lower wear rate under other braking conditions,and its friction surface is smoother.Increasing the initial braking speed can promote the formation of a friction film dominated by oxide films on the surfaces of the two friction materials,and the friction film of the copper-coated SiO2 containing material is more uniform,so the protection effect is better,that is,the wear rate is low.

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刘军锋,张鑫,上官宝,商宏飞,傅丽华,杜三明. SiO2表面金属包覆处理对铜基粉末冶金材料制动摩擦磨损性能的影响[J].润滑与密封,2023,48(6):15-24.
LIU Junfeng, ZHANG Xin, SHANGGUAN Bao, SHANG Hongfei, FU Lihua, DU Sanming. Effect of SiO2 Surface Metal Coating Treatment on the Braking Friction and Wear Properties of Cu-Based Powder Metallurgy Materials[J]. Lubrication Engineering,2023,48(6):15-24.

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  • 在线发布日期: 2023-06-21
  • 出版日期: 2023-06-15