Aimed at the problem of sudden failure of high temperature lubrication performance of the lubricating oil,three micronano level silver pyrazolemethylpyridine complexes of high temperature adaptive (complex1[Ag(LMe)\]2(BF4)2，complex 2 [Ag(Li-Pr)n](BF4)n and complex 3 [Ag(LMe)(NO3)]2).The tribological properties of silver pyrazole methylpyridine complexes as lubricating oil additives were investigated,and the friction and wear mechanism was analyzed.The results show that complexes 1 and 2 exhibit good antiwear and friction reducing properties in the temperature range from 200 ℃ to 400 ℃,and complex 3 does not have the expected antiwear and friction reducing effects due to serious agglomeration.The complex 1 with a layered structure has the best antiwear and friction reducing effect,and the lubricating oil with an mass fraction of 0.5% complex 1 has the best lubricating performance.The results of thermogravimetric analysis show that the silver particles formed by silver pyrazolemethylpyridine complexes at high temperature can effectively fill the pits on the friction surface,make the wear form of the friction pair change from twobody wear to threebody wear,and reduce the wear level of the material surface.Therefore,silver pyrazole methylpyridine complexes can be used as a controllable backup lubricating additive.