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综采工作面刮板输送机槽帮腐蚀和磨损机制*
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清华大学摩擦学国家重点实验室开放基金项目(SKLTKF20B11);中央高校基本科研业务费项目(2021YQJD21);大学生创新训练项目(202104021)


Corrosion and Wear Mechanism of Groove Side of Scraper Conveyor in Fully Mechanized Mining Face
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    摘要:

    煤炭开采过程中,由于井下环境苛刻,刮板输送机的槽帮受到腐蚀和磨损作用,导致其使用寿命和可靠性降低。为揭示槽帮腐蚀和磨损机制从而为槽帮的防护和新型耐磨材料的开发提供理论支撑,对刮板输送机的主要材料30SiMn钢进行磨料磨损试验,并观察磨损形貌以揭示其磨损机制;通过电化学试验、腐蚀浸泡试验,结合计算机模拟揭示其腐蚀机制。结果表明:室温下30SiMn钢平均硬度为220.94HB,在磨料的切向切削作用下,30SiMn钢表面出现了犁沟区与微切削区,且划痕深度大、截面宽,磨料切削作用是磨损失效的主要原因;30SiMn钢的自腐蚀电流为1.2074×10-6 A/cm2,年化腐蚀速度为0113 8 mm/年;30SiMn钢在矿井水环境中主要以晶界腐蚀为主,晶界处率先发生腐蚀,随时间推移,材料表面有团絮状物质产生且腐蚀现象加剧,最终材料由晶界处产生裂缝并伴随着剥落现象的发生;在结构稳定时,Fe对Cl-、Ca2+、Na+、H2O、SO2-4吸附距离分别为0.2364、0.242 0、0.310 5、0.247 0、0.197 6 nm;Fe对Cl-、Ca2+、Na+、H2O、SO2-4吸附能分别为-1.33、-10.06、-19.3、-5.46、-0.43 eV,说明在稳定状态下Fe对5种离子(分子)均存在吸附关系,吸附离子对能量较大的晶界产生腐蚀作用,证实了浸泡实验结果。

    Abstract:

    In the process of coal mining,due to the harsh underground environment,the groove side of the scraper conveyor is corroded and worn,which reduces its service life and reliability.To reveal the corrosion and wear mechanism of the groove side,so as to provide theoretical support for the protection of the groove side and the development of new wear-resistant materials,the abrasive wear test was performed on 30SiMn steel,the main material of the scraper conveyor,and the wear morphology was observed to reveal its wear mechanism.The electrochemical tests,corrosion immersion tests,and computer simulations were combined to reveal its corrosion mechanism.The results show that the average hardness of 30SiMn steel at room temperature is 220.94HB.Under the tangential cutting action of the abrasive,the 30SiMn steel has furrow and micro-cutting areas on the surface,and the depth of the scratches is large and the cross section is wide.The abrasive cutting effect is the main reason of wear failure.The self-corrosion current of 30SiMn steel is 1.207 4×10-6 A/cm2,and the annual corrosion rate is 0.113 8 mm.30SiMn steel is mainly corroded at grain boundaries in the mine water environment,and the corrosion occurs first at the grain boundaries.As time goes by,clusters of flocculent substances are generated on the surface of the material and the corrosion phenomenon intensifies.Eventually,the material produces cracks from the grain boundaries and is accompanied by the occurrence of spalling.When the structure is stable,the adsorption distances of Fe to Cl-,Ca2+,Na+,H2O,SO2-4 are 0.236 4,0.242 0,0.310 5,0.247 0,0.197 6 nm,respectively.The adsorption energies of Fe to Cl-,Ca2+,Na+,H2O,SO-24 are -1.33,-10.06,-19.3,-5.46,-0.43 eV,respectively.It shows that there is an adsorption relationship between Fe and five kinds of ions (molecules) in the stable state,and the adsorbed ions have a corrosive effect on the grain boundaries with large energy,which verifies the results of immersion experiment.

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李平辉,胡纯,柳明多,范秦政,李悦,范磊.综采工作面刮板输送机槽帮腐蚀和磨损机制*[J].润滑与密封,2022,47(9):105-110.
LI Pinghui, HU Chun, LIU Mingduo, FAN Qinzheng, LI Yue, FAN Lei. Corrosion and Wear Mechanism of Groove Side of Scraper Conveyor in Fully Mechanized Mining Face[J]. Lubrication Engineering,2022,47(9):105-110.

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  • 在线发布日期: 2023-01-11
  • 出版日期: 2022-09-15